期刊
ACS NANO
卷 11, 期 10, 页码 10373-10383出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.7b05442
关键词
cesium lead halide perovskite nanocrystals; photoluminescence quantum yield; perovskite quantum dot; stable perovskite; colloidal nanoparticles
类别
资金
- Japan Science and Technology Agency (JST) CREST
- JST PRESTO
- MEXT KAKENHI [26286013, 17H02736]
- UEC
- Grants-in-Aid for Scientific Research [17H02736] Funding Source: KAKEN
Perovskite quantum dots (QDs) as a new type of colloidal nanocrystals have gained significant attention for both fundamental research and commercial applications owing to their appealing optoelectronic properties and excellent chemical processability. For their wide range of potential applications, synthesizing colloidal QDs with high crystal quality is of crucial importance. However, like most common QD systems such as CdSe and PbS, those reported perovskite QDs still suffer from a certain density of trapping defects, giving rise to detrimental nonradiative recombination centers and thus quenching luminescence. In this paper, we show that a high room-temperature photoluminescence quantum yield of up to 100% can be obtained in CsPbI3 perovskite QDs, signifying the achievement of almost complete elimination of the trapping defects. This is realized with our improved synthetic protocol that involves introducing organolead compound trioctylphosphinePbI(2) (TOP-PbI2) as the reactive precursor, which also leads to a significantly improved stability for the resulting CsPbI3 QD solutions. Ultrafast kinetic analysis with time-resolved transient absorption spectroscopy evidence the negligible electron or hole-trapping pathways in our QDs, which explains such a high quantum efficiency. We expect the successful synthesis of the ideal perovskite QDs will exert profound influence on their applications to both QD-based light-harvesting and -emitting devices.
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