期刊
ENERGY STORAGE MATERIALS
卷 9, 期 -, 页码 78-84出版社
ELSEVIER
DOI: 10.1016/j.ensm.2017.06.012
关键词
Li-S battery; Polydopamine; MnO2; S@MnO2 hybrid material; Polysulfide inhibitor
资金
- National Natural Science Foundation of China [51622102, 51231003, 51571124]
- Ministry of Education of China [IRT-13R30]
- MOST [2016YFB0901502]
- 111 Project [B12015]
Sulfur is a promising alternative lithium battery cathode for its low cost, abundance, and high specific capacity. However, issues of rapid capacity decay and low coulombic efficiency hamper its practical application pace owing to polysulfides dissolution. Despite efforts on hybridizing sulfur with metal oxides to solve these issues are considered to be effective, the synthesis of hybrid materials is always tedious. Herein, S@MnO2 hybrid material was synthesized via a green method at room temperature. We encapsulate S spheres in poly-dopamine (PDA) by in-situ polymerization of dopamine. The formed PDA shell is served as reducing agent and sacrificial template to transform KMnO4 into delta-MnO2 shell without adding any other agents (such as acid). delta-MnO2 encapsulates the S spheres uniformly and succeeded in entrapping polysulfides when S@MnO2 used for Li-S battery, endowing the S@MnO2 cathode with high reversible capacity, improved cycling stability, and satisfied coulombic efficiency. Moreover, this method could be adopted for hybridizing d-MnO2 with diverse materials (such as CNTs@MnO2) in mild reaction environment (ambient pressure and temperature), exhibiting an extensive application on constructing Mn-based oxide hybrid functional materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据