期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 41, 页码 12712-12717出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707006
关键词
alkenes; iron; ketones; oxidation; radicals
资金
- Natural Science Foundation of Jiangsu Province [BK20161553]
- Natural Science Foundation of Jiangsu Provincial Colleges and Universities [16KJB150019]
- Natural Science Foundation of China [21776139,21302099]
- Qing Lan project
- Priority Academic Program Development of Jiangsu Higher Education Institutions
A practical and general iron-catalyzed Wacker-type oxidation of olefins to ketones is presented, and it uses ambient air as the sole oxidant. The mild oxidation conditions enable exceptional functional-group tolerance, which has not been demonstrated for any other Wacker-type reaction to date. The inexpensive and nontoxic reagents [iron(II) chloride, polymethylhydrosiloxane, and air] can, therefore, also be employed to oxidize complex natural-product-derived and polyfunctionalized molecules.
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