期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 41, 页码 12538-12542出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706360
关键词
copper(I) cyanide; cyanation; meta-C-H activation; palladium; pyrimidines
资金
- SERB, India
- UGC-India
- DST-India [YSS/2014/000530]
An easily removable pyrimidine-based auxiliary has been employed for the remote meta-C-H cyanation of arenes. The scope of this Pd-catalyzed cyanation reaction using copper(I) cyanide as the cyanating agent was demonstrated with benzylsilanes, benzylsulfonates, benzylphophonates, phenethylsulfonates, and phenethyl ether derivatives. The method was utilized for the synthesis of pharmaceutically valuable precursors.
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