期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 39, 页码 33379-33388出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.6b14604
关键词
AgInS(2)quantum dots; electron transfer; emission quenching; solar cells
资金
- Division of Chemical Sciences, Geosciences and Biosciences, Basic Energy Sciences, Office of Science, U.S. Department of Energy [DE-FC02-04ER15533]
- Arthur J. Schmitt Leadership Fellowship
- Comision Nacional de Investigacion Cientifica y Tecnologica (CONICYT) [72110038]
Multinary quantum dots such as AgInS2 and alloyed AgInS2-ZnS are an emerging class of semiconductor materials for applications in photovoltaic and display devices. The nanocrystals of (AgInS2)(x)-(ZnS)(1-x) (for x = 0.67) exhibit a broad emission with a maximum at 623 nm and interact strongly with TiO2 nanostructures by injecting electrons from the excited state. The electron transfer rate constant as determined from transient absorption spectroscopy was 1.8 X 10(10) s(-1) . The photovoltaic performance was evaluated over a period of a few weeks to demonstrate the stability of AgInS2-ZnS when utilized as sensitizers in solar cells. We report a power conversion efficiency of 2.25% of our champion cell 1 month after its fabrication. The limitations of AgInS2-ZnS nanocrystals in achieving greater solar cell efficiency are discussed.
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