期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 42, 页码 12930-12934出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706557
关键词
cycloaddition; ketones; heterocycles; hydrogen bonds; organocatalysis
资金
- Department of Science and Technology (DST), SERB, New Delhi [EMR/2015/000860]
- Council of Scientific and Industrial Research (CSIR), New Delhi
- University Grants Commission (UGC), New Delhi
Pharmaceutically and structurally important methanobenzo[7]annulenes were synthesized in very good yields with excellent enantio- and diastereoselectivities through an unprecedented organocatalytic formal [3+2]cycloaddition from readily available 2-alkyl-3-hydroxynaphthalene-1,4-diones and alkyl vinyl ketones.
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