期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 40, 页码 35253-35259出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b11277
关键词
white-light-emitting diode (WLED); metal organic framework (MOF); visible-light communication (VLC); energy transfer; luminescent materials
资金
- National Natural Science Foundation
- Ministry of Science and Technology of the P. R. China [NNSFC21671162, 2016YFA0200700, NNSFC21471126, NNSFC61601439]
- National Thousand Talents Program of the P. R China
- Xiamen University
A dye@metal-organic framework (MOP) hybrid was used as a fluorophore in a white-light-emitting diode (WLED) for fast visible-light communication (VLC). The white light was generated from a combination of blue emission of the 9,10-dibenzoate anthracene (DBA) linkers and yellow emission of the encapsulated Rhodamine B molecules. The MOF structure not only prevents dye molecules from aggregation-induced quenching but also efficiently transfers energy to the dye for dual emission. This light-emitting material shows emission lifetimes of 1.8 and 5.3 ns for the blue and yellow components, respectively, which are significantly shorter than the 200 ns lifetime of Y3Al5O12:Ce3+ in commercial WLEDs. The MOF-WLED device exhibited a modulating frequency of 3.6 MHz for VLC, six times that of commercial WLEDs.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据