期刊
CHEMICAL REVIEWS
卷 117, 期 19, 页码 12564-12580出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.7b00385
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资金
- Robert A. Welch Foundation [F-0038]
- NIH-NIGMS [RO1-GM069445]
Whereas numerous asymmetric methods for formation of quaternary carbon stereocenters in cyclic systems have been documented, the construction of acyclic quaternary carbon stereocenters with control of absolute stereochemistry remains a formidable challenge. This Review summarizes enantioselective methods for the construction of acyclic quaternary carbon stereocenters from achiral or chiral racemic reactants via transition metal catalysis.
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