期刊
ELECTROCHIMICA ACTA
卷 252, 期 -, 页码 532-540出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.09.030
关键词
Double perovskite bifunctional catalysts; Oxygen evolution reactions; Oxygen reduction reaction; Impedance spectroscopy
资金
- Indian National Science Academy (INSA) under Young Scientist Project Scheme [SP/YSP/102/2014/1065]
Perovskite oxides are prominent materials as the bifunctional electrocatalysts for both oxygen reduction/evolution reactions (ORR/OER) for the electrochemical energy conversion and storage using regenerative fuel cells and rechargeable metal-air batteries. In this work, a quadruple perovskite CaCu3Ti4O12 has been synthesized oxalate precursor route. X-ray diffraction pattern shows phase purity of the synthesized electrocatalyst. The synthesized CCTO electrocatalyst have crystallite size of 26 nm. Electrochemical investigations reveal that CCTO exhibit efficient catalytic activity. More interestingly, an extremely high OER activity is observed for CCTO electrocatalysts which is found superior than similar class of perovskites. Additionally, CCTO shows efficient ORR activity with an onset potential of 0.83 V which is better than that of Pt/C catalyst (approximate to 0.94 V). These results demonstrate the significant potential of CCTO perovskite as a bifunctional electrode material for alkaline fuel cells and metal-air batteries. (C) 2017 Elsevier Ltd. All rights reserved.
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