期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 59, 页码 14860-14865出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702857
关键词
polyoxometalates; conducting oligomers; organic-inorganic hybrid; self-assembly; redox-responsiveness
资金
- National Natural Science Foundation of China (NSFC) [21225103, 21631007, 21221062]
A redox-responsive hybrid of polyoxometalate and conducting oligomer including its self-assemblies with controllable morphologies are reported. To this end, a hybrid molecule, containing a Lindqvist hexamolybdate as the polar head group and N,N-bis(4-amino-2,6-dimethylphenyl)-1,4-quinonediimine as the redox-responsive and aggregating group, is prepared. This hybrid exhibits redox-responsive behavior with controllable assembling morphological transition from spherical vesicles to short cylindrical vesicles. Besides, the hybrid-based self-assemblies are transferred to the surface, thus the surface wettability can be well-tuned owing to the morphological transitions of the self-assemblies. By marrying conducting materials with polyoxometalate chemistry, this research opens a new horizon of polyoxometalate-based self-assembled systems with potential applications in functional materials.
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