期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 44, 页码 13800-13804出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201706602
关键词
doping; iron; oxygen reduction reaction; sulfur; synergistic effects
资金
- National Natural Science Foundation of China [21677171, 21505154, 51671003]
- Xinjiang International Science and Technology Cooperation Project [20166010]
- National Key Research and Development Program of China [2016YFB0100201]
- 1000-Talent Program (Recruitment Program of Global Expert, in Chinese: Qian-Ren-Ji-Hua)
Various advanced catalysts based on sulfur-doped Fe/N/C materials have recently been designed for the oxygen reduction reaction (ORR); however, the enhanced activity is still controversial and usually attributed to differences in the surface area, improved conductivity, or uncertain synergistic effects. Herein, a sulfur-doped Fe/N/C catalyst (denoted as Fe/SNC) was obtained by a template-sacrificing method. The incorporated sulfur gives a thiophene-like structure (C-S-C), reduces the electron localization around the Fe centers, improves the interaction with oxygenated species, and therefore facilitates the complete 4e(-) ORR in acidic solution. Owing to these synergistic effects, the Fe/SNC catalyst exhibits much better ORR activity than the sulfur-free variant (Fe/NC) in 0.5m H2SO4.
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