期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 44, 页码 13666-13669出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707021
关键词
allylic compounds; amination; reaction mechanisms; regioselectivity; rhodium
资金
- National Science Foundation [CHE-1362502, CHE-1531620]
- Laney Graduate School of Emory University
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1531620] Funding Source: National Science Foundation
A method for catalytic intermolecular allylic C-H amination of trans-disubstituted olefins is reported. The reaction is efficient for a range of common nitrogen nucleo-philes bearing one electron-withdrawing group, and proceeds under mild reaction conditions. Good levels of regioselectivity are observed for a wide range of electronically diverse trans-beta-alkyl styrene substrates.
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