4.7 Article

Cooperative self-assembly and gelation of organogold(I) complexes via hydrogen bonding and aurophilic Au• • •Au interactions

期刊

CHEMICAL COMMUNICATIONS
卷 53, 期 84, 页码 11552-11555

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc05613c

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资金

  1. National Natural Science Foundation of China [21674106]
  2. Fundamental Research Funds for the Central Universities [WK3450000001]
  3. CAS Youth Innovation Promotion Association [2015365]
  4. Open Research Fund of State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences

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With the synergistic combination of intermolecular Au(I)-Au(I) and hydrogen bonding interactions, a rod-coil alkynyl-gold(I)-isocyanide monomer tends to form supramolecular fibers and gels via a cooperative nucleation-elongation self-assembly mechanism, which display Ag(I) ion-triggered responsiveness.

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