期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 31, 期 11, 页码 -出版社
WILEY
DOI: 10.1002/aoc.3790
关键词
alcohol; BrOnsted-Lewis acidic ionic liquids; hexamethyldisilazane; HMDS; phenol; silylation
资金
- Chemistry and Chemical Engineering Research Center of Iran
A practical and highly efficient silylation of alcohol and phenol derivatives with hexamethyldisilazane (HMDS) using acidic ionic liquids under mild reaction conditions is described. A series of BrOnsted as well as BrOnsted-Lewis acidic ionic liquids were prepared and their performance investigated for the silylation of a wide variety of alcohols and phenols with HMDS. Imidazole- as well as N-methyl-2-pyrrolidone-based acidic ionic liquids have a higher catalytic activity for the protection of sensitive, hindered alcohols and phenols, thus providing an environmentally begin and versatile alternative to current acid catalysts. In addition, the acidic ionic liquids are reusable, being recovered easily and reused several times without significant deterioration in catalytic activity.
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