期刊
CARBON
卷 124, 期 -, 页码 111-122出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2017.08.034
关键词
-
资金
- National Natural Science Foundation P.R. China [21677106, 21537003]
- Science and Technology Commission of Shanghai Municipality [14DZ2261100]
- State Key Laboratory of Pollution Control and Resource Reuse Foundation [PCRRF16007]
A promising activated iron-doped carbon aerogel (AFeC) possessing high adsorption capacity and self-cleaning ability via generated (OH)-O-center dot radicals was fabricated and applied to remove dimethyl phthalate (DMP). Around 90% of the DMP (50 ppm) was first adsorbed on the surface of a DMP-imprinted AFeC electrode and then further catalytically oxidized by surface (OH)-O-center dot produced via an electro-Fenton reaction. DMP removal of 98% can be achieved in 150 min in the heterogeneous electro-Fenton process. The addition of Fe-0 favoured the generation of graphene sheets of amorphous carbon and then provided strong pi-pi interaction with aromatic pollutants. In addition to iron, a DMP molecular template was also introduced to AFeC to create special molecular imprinting affinity for DMP. The CO2-N-2 activation treatment increased the porosity and enriched the hydroxyl and quinone groups (C-O and C=O). The high DMP adsorption capacity of the DMP-imprinted AFeC electrode can be ascribed to the following mechanism: (i) electrostatic interaction; (ii) hydrophobic interaction; (iii) pi-pi electron-donor-acceptor interactions; (iv) molecular imprinting affinity between template molecules and imprinted sites. Thus, this carbon-based material is promising to be potentially applied in the removal of DMP containing wastewater through integrated adsorption and degradation. (C) 2017 Elsevier Ltd. All rights reserved.
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