期刊
DALTON TRANSACTIONS
卷 46, 期 36, 页码 12293-12305出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt02759a
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资金
- Centre National de la Recherche Scientifique (CNRS)
A series of NHC pre-ligands featuring a pendant phosphonium moiety attached to N' position through a propyl linker was readily obtained upon quaternization of N-mesityl-and N-methyl-imidazole, or N-mesityl-imidazoline using (3-bromo-propyl)-triphenylphosphonium bromide. Reactions of the resulting dicationic salts with [PdCl(allyl)] 2 in the presence of K2CO3 afforded the anticipated NHC-ligated Pd(II) metal complexes in high yields. Further treatment of the latter complexes with tBuOK induced a deprotonation of the carbon atom adjacent to the phosphonium moiety and the formation of the corresponding C, C-chelating NHC-phosphonium ylide Pd(II) complexes. Investigation of an alternative synthetic route involving a silver transmetallation reaction incidentally allowed isolation and full characterization of an unusual dimeric tetranuclear NHC Ag(I) complex of general formula [(NHC similar to P+)(2)(Ag4Br6)(2-)].
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