期刊
ANALYTICAL METHODS
卷 9, 期 30, 页码 4341-4348出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ay01494e
关键词
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资金
- National Natural Science Foundation of China [61301037]
- Henan Science and Technology Cooperation Project [172106000014]
- Foundation of Henan Educational Committee [13A550194]
- Key Project of Zhengzhou [20120663]
- Plan for Scientific Innovation Talent of Henan University of Technology [2012CXRC02]
- Fundamental Research Funds for the Henan Provincial Colleges and Universities [2014YWQQ05]
- Youth Backbone Teacher Training Program of Henan University of Technology
A new sensor using a glassy carbon electrode modified with graphene and Au nanoparticles (Gr/Au/GCE) was designed to investigate the electrochemical behavior of furazolidone (FZD). The morphology and nature of the modified electrode were characterized by UV-vis spectroscopy, transmission electron microscopy (TEM) and electrochemical impedance spectroscopy (EIS). FZD was reduced on the Gr/Au/GCE at lower potentials with a higher peak current, compared to the bare GCE, through an irreversible process. These results arose from the synergistic effect of the deposited Gr/Au suspension on the GCE. For this article, several parameters, such as pH, scan rate, and the amount of modifier had been studied. Under optimal conditions, amperometry (AMP) and differential pulse stripping voltammetry (DPSV) were applied to the determination of FZD. Linear dynamic ranges of 1- 674 mmol L-1, and 0.02- 0.14 mmol L-1 and 0.14-400 mmol L-1 with detection limits of 0.64 mmol L-1 and 0.0126 mmol L-1 were obtained using AMP and DPSV, respectively. The sensor was also successfully applied to the determination of FZD in real samples, obtaining satisfactory recoveries.
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