期刊
DALTON TRANSACTIONS
卷 46, 期 37, 页码 12434-12437出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7dt02946b
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资金
- Swiss National Science Foundation [CRSII2_160749/1]
- Swiss National Science Foundation (SNFS) [206021_150638/1]
- Swiss National Science Foundation (SNF) [CRSII2_160749] Funding Source: Swiss National Science Foundation (SNF)
This communication presents the first synthesis of nanoconfined Lithium closo-borate, Li2B12H12, using nanoporous SiO2 as scaffold. The yield of Li2B12H12 is up to 94 mol%. The as-synthesized nanoconfined Li2B12H12 exhibits a structural transition around 380 degrees C and conversion to H-deficiency Li2B12H12- x at 580 degrees C.
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