期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 21, 页码 3826-3830出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700619
关键词
benzamides; metal-free arylation; aryl radicals; visible light; arylazo sulfones
资金
- Lombardy Region, Italy [2015-0756]
- Cariplo Foundation, Italy [2015-0756]
The photochemical metal-free carboamidation of aryl radicals has been exploited for the preparation of aromatic amides, including hetero-and polyaromatic derivatives, under visible light irradiation of arylazo sulfones in the presence of isocyanides in aqueous acetonitrile. The process was useful for the smooth preparation of the antidepressant moclobemide.
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