4.6 Article

Metal-Based Diversity for Crystalline Metal-Fullerene Frameworks

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 63, 页码 15864-15868

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201703709

关键词

cadmium; calcium; copper; fullerenes; metal-organic frameworks

资金

  1. Fonds der Chemischen Industrie
  2. DFG [SPP 1362/2, BE 4808/1-2, MU 1562/5-2]
  3. Bavarian State (Collaboratory Research Network Solar Technologies Go Hybrid)
  4. Bavarian State (Bavarian Polymer Institute)

向作者/读者索取更多资源

Four different three-dimensional metal-fullerene frameworks were synthesized through polymerization of two C-60-derived dodecaacids with varying alkyl spacers in the presence of Ca2+, Cu2+ or Cd2+ ions. Structural analysis of the frameworks was performed by single-crystal Xray diffraction and porosity of the materials was investigated by sorption measurements.

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