期刊
CHINESE JOURNAL OF POLYMER SCIENCE
卷 35, 期 12, 页码 1447-1456出版社
SPRINGER
DOI: 10.1007/s10118-017-2003-9
关键词
Conjugated polymer; Helical polymer; Polyisocyanide; Block copolymer; Living polymerization
资金
- National Natural Science Foundation of China [21622402, 51673057, 21574036]
- 1000 plan Program for Young Talents of China
Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing pi-conjugated polythiophene and helical polyisocyanide segments by using a nickel(II) complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights (M(n)s) and narrow molecular weight distributions (M-w/M(n)s). By using this method, a family of block copolymers with expected structure and tunable compositions can be facilely prepared. Introducing functional groups onto the pendant, these block copolymers can exhibit interesting self-assembly property, tunable light emission and multi-responsiveness.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据