期刊
CHIRALITY
卷 29, 期 11, 页码 663-669出版社
WILEY
DOI: 10.1002/chir.22765
关键词
amino acids; diamines; circular dichroism; absolute configuration; enantiomeric excess; chiral amplification
资金
- Division of Chemistry [CHE-1464547]
- NSF [CHE-1464547]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1464547] Funding Source: National Science Foundation
Three Cu(I) complexes derived from stereodynamic diphosphine ligands were synthesized and used for chirality sensing. The coordination of diamines and amino acids to these complexes generates distinct circular dichroism signals. The chiroptical sensor response allows determination of the absolute configuration and the enantiomeric excess of the analyte at low concentrations. This method is operationally simple, fast, and attractive for high-throughput sensing applications.
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