期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 44, 页码 13762-13766出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201708169
关键词
high oxidation states; nickel; redox chemistry; sulfur ligands
资金
- CREST, JST [JPMJCR13L3]
- JSPS KAKENHI [15K21127]
- Tokuyama Science Foundation
- Project for Creation of Research Platforms and Sharing of Advanced Research Infrastructure, Japan [R1545, S16006, S16026]
- Grants-in-Aid for Scientific Research [15K21127, 16K17945] Funding Source: KAKEN
Three oxidation states (+2, +3, +4) of an octahedral nickel center were stabilized in a newly prepared RhNiRh trinuclear complex, [Ni{Rh(apt)(3)}(2)](n+) (apt = 3-aminopropanethiolate), in which the nickel center was bound by six thiolato donors sourced from two redox-inert fac[Rh-III(apt)(3)] octahedral units. The three oxidation states of the octahedral nickel center were fully characterized by single-crystal X-ray crystallography, as well as spectroscopic, electrochemical, and magnetic measurements; all three were interconvertible, and the conversion was accompanied by changes in color, magnetism, and Jahn-Teller distortion.
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