期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 59, 页码 14728-14732出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201703905
关键词
1,2-addition; density functional theory; dihydrogen activation; hydride; scandium
资金
- National Natural Science Foundation of China [21325210, 21421091]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
Dihydrogen is easily activated by a scandium terminal imido complex containing the weakly coordinated THF. The reaction proceeds through a 1,2-addition mechanism, which is distinct from the sigma-bond metathesis mechanism reported to date for rare-earth metal-mediated H-2 activation. This reaction yields a scandium terminal hydride, which is structurally well-characterized, being the first one to date. The reactivity of this hydride is reported with unsaturated substrates, further shedding light on the existence of the terminal hydride complex. Interestingly, the H-2 activation can be reversible. DFT investigations further eludciate the mechanistic aspects of the reactivity of the scandium anilido-terminal hydride complex with PhNCS but also on the reversible H-2 activation process.
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