4.7 Article

Stereoselective synthesis of bicyclo[3.n.1]alkenone frameworks by Lewis acid-catalysis

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CHEMICAL COMMUNICATIONS
卷 53, 期 82, 页码 11353-11356

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc06400d

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An intermolecular cyclization of alkynyl enones with cyclic ketones for the synthesis of bicyclo[3.n.1]alkenones is reported. This protocol exhibits a high functional group tolerance and provides access to a variety of bicyclic systems found as skeletons in many natural products.

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