期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 58, 页码 14554-14562出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201702742
关键词
density functional calculations; liquid crystals; soft matter; X-ray scattering
资金
- QinetiQ
- EPSRC [EP/M020584/1, EP/J007714/1]
- EPSRC Platform Grant [EP/D055261/1]
- EPSRC core capabilities grant [EP/K039660/1]
- EPSRC [EP/J007714/1, EP/D055261/1, EP/K039660/1, EP/L012375/1, EP/M020584/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/J007714/1, EP/L012375/1, EP/M020584/1, EP/K039660/1, EP/D055261/1] Funding Source: researchfish
Recently, a polar, rod-like liquid-crystalline material was reported to exhibit two distinct nematic mesophases (termed N and N-X) separated by a weakly first-order transition. Herein, we present our initial studies into the structure-property relationships that underpin the occurrence of the lower-temperature nematic phase, and report several new materials that exhibit this same transformation. We have prepared material with significantly enhanced temperature ranges, allowing us to perform a detailed study of both the upper- and lower-temperature nematic phases by using small-angle X-ray scattering. We observed a continuous change in d spacing rather than a sharp change at the phase transition, a result consistent with a transition between two nematic phases, structures of which are presumably degenerate.
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