期刊
ANALYTICA CHIMICA ACTA
卷 990, 期 -, 页码 135-140出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2017.07.018
关键词
Spectrophotometric method; Nitrite detection; Nitrosonium ion; Organometallic complex; Tap water; Human urine
资金
- Hong Kong Innovation and Technology Commission [ITS/296/15]
- Research Grants Council of Hong Kong SAR [CityU 11228316, T42-103/16-N]
- Science Technology and Innovation Committee of Shenzhen Municipality [JCYJ20160229165216275]
- Shenzhen Research Institute, City University of Hong Kong
Quantitative determination of nitrite ion (NO2-) is of great importance in environmental and clinical investigations. A rapid visual and spectrophotometric assay for NO2- detection was developed based on a newly designed ruthenium complex, [Ru(npy)([9]aneS3)(CO)](ClO4) (denoted as RuNPY; npy _ 2-(1-naphthyl)pyridine, [9] aneS3 = 1,4,7- trithiacyclononane). This complex traps NO+ produced in acidified NO2- solution, and yields observable color change within 1 min at room temperature. The assay features excellent dynamic range (1-840 mmol L-1) and high selectivity, and its limit of detection (0.39 mmol L-1) is also well below the guideline values for drinking water recommended by WHO and U.S. EPA. Practical use of this assay in tap water and human urine was successfully demonstrated. Overall, the rapidity and selectivity of this assay overcome the problems suffered by the commonly used modified Griess assays for nitrite determination. (C) 2017 Elsevier B.V. All rights reserved.
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