期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 13, 期 -, 页码 2131-2137出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.13.211
关键词
bisphenol A; carbon dioxide uptake; hydrogen storage; OH-containing; porous organic polymers
资金
- National Natural Science Foundation of China [21574032]
- Ministry of Science and Technology of China [2014CB932200]
We successfully employed bisphenol A and several different formyl-containing monomers as useful building blocks to construct a series of hydroxy-group-containing porous organic polymers in a sealed tube at high temperature. Fourier transform infrared and solid-state C-13 CP/MAS NMR spectroscopy are utilized to characterize the possible structure of the obtained polymers. The highest Brunauer-Emmet-Teller specific surface area of the phenolic-resin porous organic polymers (PPOPs) is estimated to be 920 m(2) g(-1). The PPOPs exhibit a highest carbon dioxide uptake (up to 15.0 wt % (273 K) and 8.8 wt % (298 K) at 1.0 bar), and possess moderate hydrogen storage capacities ranging from 1.28 to 1.04 wt % (77 K) at 1.0 bar. Moreover, the highest uptake of methane for the PPOPs is measured as 4.3 wt % (273 K) at 1.0 bar.
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