4.6 Article

Platinum Complexes Bearing Bulky N-Heterocyclic Carbene Ligands as Efficient Catalysts for the Fully Selective Dimerization of Terminal Alkynes

期刊

CHEMCATCHEM
卷 9, 期 19, 页码 3627-3631

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201700580

关键词

alkynes; carbene ligands; dimerization; homogeneous catalysis; platinum

资金

  1. National Centre for Research and Development (Poland) [PBS2/A5/40/2014]
  2. Foundation for Polish Science [POMOST/2012-6/14]
  3. European Union under the European Regional Development Fund

向作者/读者索取更多资源

New platinum(0) complexes of the general formula [(NHC)Pt(dvtms)] (dvtms=1,3-divinyltetramethyldisiloxane) containing bulky N-heterocyclic carbene (NHC) ligands were prepared, characterized, and found to be catalytically active in the fully regio- and stereoselective dimerization of terminal acetylenes.

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