期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 12, 期 19, 页码 2524-2527出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201700939
关键词
arenes; graphene oxide; initiator-free; metal-free; trifluoromethylation
资金
- National Natural Science Foundation of China [21402168]
- Scientific Research Foundation of Hunan Provincial Education Department [15B232]
- Hunan Collaborative Innovation Center of Chemical Engineering and Technology with Environmental Benignity and Effective Resource Utilization
The direct C-H trifluoromethylation of arenes catalyzed by graphene oxide (GO) under safe conditions is described. This strategy is metal-free, initiator-free, safe, and scalable. It employs a readily available CF3 source and the reaction can be easily controlled to obtain a mono-trifluorinated product. This method opens a new avenue for GO-catalyzed chemistry.
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