期刊
CHEMISTRY LETTERS
卷 46, 期 12, 页码 1692-1700出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.170834
关键词
Synthetic method; C-C bond cleavage; Radical
The C-C bond located at the beta-position of an alkoxy radical readily breaks to form an alkyl radical along with a carbonyl compound. Such processes are called beta-scission or beta-fragmentation. They possibly proceed without any assistance of ring strain, and have recently attracted renewed attention as the key elementary step to transform alcohols in a unique fashion. Summarized in this Highlight Review are synthetic transformations of alcohols through beta-scission of alkoxy radical intermediates.
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