期刊
CHEMICAL RECORD
卷 17, 期 10, 页码 1059-1069出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201700008
关键词
practical synthesis; enantiomer; organocatalyst; amino acid; Mannich
资金
- MEXT, Japan
- International Scientific Partnership Program ISPP at King Saud University through ISPP [0072]
- Grants-in-Aid for Scientific Research [26220803, 17H06450] Funding Source: KAKEN
In this account, we describe our recent developments in organocatalyzed asymmetric methodologies for the practical synthesis of both enantiomers. The synthesis of both enantiomeric products by using both enantiomeric catalysts is the most traditional way. In addition, use of two pseudoenantiomeric catalysts provides a more practical approach for the synthesis of both enantiomeric products. Even more efficient is the use of a single enantiomeric catalyst in the presence or absence of certain additives for obtaining both enantiomeric products. These three different strategies are illustrated by using certain organocatalyzed asymmetric approaches.
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