期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 46, 页码 40265-40272出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b12568
关键词
metallic sodium; SEI film; 3D host; conversion reaction; molybdenum disulfide; sodium disulfide
资金
- National Science Foundation of China [51572007, 51622203]
Metallic sodium is a promising anode for sodium-based batteries, owing to its high theoretical capacity (1165 mAh g(-1)) and low potential (-2.714 V vs standard hydrogen electrode). However, the growth of sodium dendrites and the infinite volume change of metallic sodium during sodium striping/plating result in a low Coulombic efficiency and poor cycling stability, generating a safety hazard of sodium-based batteries. Here, an efficient approach was proposed to simultaneously generate an artificial SEI film and 3D host for metallic sodium based on a conversion reaction (CR) between sodium and MoS2 (4Na + MoS2 = 2Na(2)S + Mo) at room temperature. In the resultant sodium-MoS2 hybrid after the conversion reaction (Na-MoS2 (CR)), the production Na2S is homogeneously dispersed on the surface of metallic sodium, which can act as an artificial SEI film, efficiently preventing the growth of sodium dendrites; the residual MoS2 nanosheets can construct a 3D host to confine metallic sodium, accommodating largely the volume change of sodium. Consequently, the Na-MoS2 (CR) hybrid exhibits very low overpotential of 25 mV and a very long cycle stability more than 1000 cycles. This novel strategy is promising to promote the development of metal (lithium, sodium, zinc)-based electrodes.
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