期刊
ULTRASONICS SONOCHEMISTRY
卷 38, 期 -, 页码 421-429出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ultsonch.2017.03.039
关键词
Magnetic graphene oxide; Sonication; Central composite design (CCD); Preconcentration; Trace determination; Mercury ions
资金
- Iran University of Science and Technology
- Iran Nanotechnology Initiative Council
In this work, the synthesis of the magnetic graphene oxide modified by 2-pyridinecarboxaldehyde thiosemicarbazone groups (Fe3O4@GO/2-PTSC) was utilized for preconcentration and determination of mercuric ions in a trace amount by inductively coupled plasma-optical emission spectrometry (ICP-OES). Characterization of the adsorbent was performed using various techniques, such as FT-IR, VSM, SEM and XRD analysis. Central composite design (CCD) under response surface methodology (RSM) was used for obtaining the most important parameters and probable interactions in variables. The variables such as adsorbent dosage, pH, desorption time, and eluent volume was optimized. These values were 8 mg, 5.4 min, 0.5 mL (HC1, 0.1 M), respectively. Sonication had an important role in shortening the adsorption time of Hg (II) ions by enhancing the dispersion of adsorbent in solution. Under the optimal conditions, the proposed method presented high enrichment factor of 193, an extraction percentage of 96.5, a detection limit of 0.0079m and a relative standard deviation (RSD %) of 1.63%. Finally, the application of the synthesized material was evaluated for preconcentration and determination of mercuric ions from foods and environmental waters samples.
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