期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 22, 页码 3888-3893出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700722
关键词
alkylation; ruthenium; sustainable synthesis; tandem process
资金
- Science and Engineering Research Board (SERB), India
- Council of Scientific & Industrial Research (CSIR)
- DST-INSPIRE
- IITK
A Ru(II) NHC complex (loading down to 0.001 mol%) catalyzed cross coupling of a broad range of aromatic, aliphatic and heterocyclic alcohols is reported. This protocol also functioned efficiently under solvent-free conditions. Remarkably, this catalytic system disclosed so far the highest TON of 288000 for the cross coupling of alcohols. Notably, this methodology was successfully applied for the one-pot synthesis of a range of flavan derivatives. A detailed DFT studies and kinetic experiments were performed to understand the reaction mechanism as well as the high reactivity of this catalytic system.
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