期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 22, 页码 3911-3916出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700655
关键词
2-quinolone; Michael addition; quaternary center; asymmetric; organocatalysis
资金
- DST
- DAE
The first organocatalytic asymmetric reaction employing 3,4-dihydro-2-quinolone has been developed leading to the synthesis of biologically important 3,3-disubstituted-dihydro-2-quinolones. Cinchona alkaloid derived bifunctional amino-thiourea catalysts were found to be the best catalysts. The products were obtained in high enantio- and good diastereoselectivities and also few synthetic transformations have been demonstrated.
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