期刊
ULTRASONICS SONOCHEMISTRY
卷 37, 期 -, 页码 94-105出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.ultsonch.2016.11.025
关键词
Cu@ Mn-ZnS-NPs-AC; Derivative spectrophotometry; Kinetic and isotherm studies; Response surface methodology; Ternary dyes; Ultrasound assisted adsorption
资金
- Graduate School and Research Council of the University of Yasouj
In this work, ultrasound-assisted adsorption of an anionic dye, sunset yellow (SY) and cationic dyes, malachite green (MG), methylene blue (MB) and their ternary dye solutions onto Cu@ Mn-ZnS-NPs-AC from water aqueous was optimized by response surface methodology (RSM) using the central composite design (CCD). The adsorbent was characterized using Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX) and EDX mapping images. The effects of various parameters such as pH, sonication time, adsorbent mass and initial concentrations of SY, MG and MB were examined. A total 33 experiments were conducted to establish a quadratic model. Cu@ Mn-ZnS-NPs-AC has the maximum adsorption efficiency (>99.5%) when the pH, sonication time, adsorbent mass and initial concentrations of SY, MG and MB were optimally set as 6.0, 5 min, 0.02 g, 9, 12 and 12 mg L-1, respectively. Sonication time has a statistically significant effect on the selected responses. Langmuir isotherm model was found to be best fitted to adsorption and adsorption capacities were 67.5 mg g(-1) for SY, 74.6 mg g(-1) for MG and 72.9 mg g(-1) for MB. Four kinetic models (pseudo-first order, pseudo-second order, Weber-Morris intraparticle diffusion rate and Elovich) were tested to correlate the experimental data and the sorption was fitted well with the pseudo-second order kinetic model. (C) 2016 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据