期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 48, 页码 15416-15420出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201707862
关键词
carbon dioxide; carboxylation; iron; thiophenol; photochemistry
资金
- National Natural Science Foundation of China [21502124, 21772129]
- 973 Project from the MOST of China [2015CB856600]
- 1000-Youth Talents Program
- Fundamental Research Funds for the Central Universities
The first thiocarboxylation of styrenes and acrylates with CO2 was realized by using visible light as a driving force and catalytic iron salts as promoters. A variety of important -thioacids were obtained in high yields. This multicomponent reaction proceeds in an atom- and redox-economical manner with broad substrate scope under mild reaction conditions. Notably, high regio-, chemo-, and diasteroselectivity are observed. Mechanistic studies indicate that a radical pathway can account for the unusual regioselectivity.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据