期刊
CHEMICAL COMMUNICATIONS
卷 53, 期 92, 页码 12469-12472出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cc07672j
关键词
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资金
- NSF [CHE 1310139, 1709086]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1709086, 1310139] Funding Source: National Science Foundation
Herein, the control of a molecular rotor using hydrogen bonding guests is demonstrated. With a properly positioned phenol substituent, the N-arylimide rotors can form an intramolecular hydrogen bond that catalyses the rotational isomerization process. The addition of the guests disrupts the hydrogen bond and raises the rotational barrier, slowing the rotation by two orders of magnitude.
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