期刊
CHINESE JOURNAL OF CHEMISTRY
卷 35, 期 12, 页码 1781-1788出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201700489
关键词
metal-catalyzed; asymmetric; fluorination; trifluoromethylthiolation; trifluoromethoxylation
资金
- National Basic Research Program of China (973) [2015CB856600]
- National Nature Science Foundation of China [21532009, 21472219, 21672236]
- Program of Shanghai Academic/Technology Research Leader [17XD1404500]
- Strategic Priority Research Program [XDB20000000]
The synthesis of fluorine-containing molecules has received intensive attention in recent years due to the great value of fluorides, however, the transition metal-catalyzed asymmetric construction of CF bonds is much less developed. This review presents the recent advancement of transition metal-catalyzed asymmetric fluorination reactions, in which the final CF bond is from reductive elimination of organometallic complexes. In addition, the perspective of the field is also provided for the future studies of asymmetric fluorinations and the related transformations, such as trifluoromethylation, trifluoromethylthiolation and trifluoromethoxylation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据