期刊
CHEMSUSCHEM
卷 10, 期 22, 页码 4403-4408出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201701371
关键词
artificial photosynthesis; calcium; manganese; photosystem II; water splitting
资金
- National Key Research and Development Program of China [2017YFA0503704]
- Strategic Priority Research Program of Chinese Academy of Sciences [XDB17030600]
- National Natural Science Foundation of China [31770258, 91427303]
The oxygen-evolving center (OEC) in photosystem II (PSII) is a unique biological catalyst that splits water into electrons, protons, and O-2 by using solar energy. Recent crystallographic studies have revealed that the structure of the OEC is an asymmetric Mn4Ca cluster, which provides a blueprint to develop man-made water-splitting catalysts for artificial photosynthesis. Although it is a great challenge to mimic the whole structure and function of the OEC in the laboratory, significant advances have recently been achieved. In this Minireview, recent progress on mimicking the natural OEC is discussed. New strategies are suggested to construct more stable and efficient new generation of catalytic materials for the water splitting reaction based on the artificial Mn4Ca cluster in the future.
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