期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 23, 页码 4147-4152出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700838
关键词
palladium-catalyzed; indole derivatives; 2-alkynyl arylazides; N-containing heterocycles
资金
- National Natural Science Foundation of China Grants [21302096, 21502093]
- Natural Science Foundation of Jiangsu Province Grants [BK20171449, BK20130962, BK20150871]
- Project Fund from the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
A novel method for the synthesis of C2-quaternary indole-3-ones via palladium-catalyzed one-pot transformation of 2-alkynyl arylazides is described. The reaction produced in moderate to excellent yields under mild conditions. This novel rearrangement of 1-H-indole-3-sulfonates represents an important contribution to the application of aryl sulfonates.
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