期刊
ACS APPLIED MATERIALS & INTERFACES
卷 9, 期 44, 页码 38959-38966出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.7b10666
关键词
silver; titanium dioxide; core-shell; nanowire; nonpolar resistive switching
资金
- European Research Council under advanced grant [321160]
- Science Foundation Ireland (SFI) AMBER Centre [SFI/12/RC/2278]
- European Research Council (ERC) [321160] Funding Source: European Research Council (ERC)
Nonpolar resistive switching (RS), a combination of bipolar and unipolar RS, is demonstrated for the first time in a single nanowire (NW) system. Exploiting Ag@TiO2 core-shell (CS) NWs synthesized by postgrowth shell formation, the switching mode is controlled by adjusting the current compliance effectively, tailoring the electrical polarity response. We demonstrate ON/OFF ratios of 10(5) and 10(7) for bipolar and unipolar modes, respectively. In the bipolar regime, retention times could be controlled up to 10(3) s, and in the unipolar mode, >10(6) s was recorded. We show how the unique dual-mode switching behavior is enabled by the defect-rich polycrystalline material structure of the TiO2 shell and the interaction between the Ag core and the Ag electrodes. These results provide a foundation for engineering nonpolar RS behaviors for memory storage and neuromorphic applications in CSNW structures.
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