期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 56, 期 51, 页码 16352-16356出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201709334
关键词
allylation; asymmetric catalysis; imines; isomerization; rhodium
资金
- European Research Council [258580]
- Engineering and Physical Sciences Research Council [EP/I004769/1, EP/I004769/2]
- University of Nottingham
- GlaxoSmithKline
- EPSRC [EP/I004769/2, EP/K038869/1, EP/I004769/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/I004769/2, EP/I004769/1, EP/K038869/1] Funding Source: researchfish
A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
