4.5 Article

Carbon Tetrabromide/Triphenylphosphine-Activated Beckmann Rearrangement of Ketoximes for Synthesis of Amides

期刊

CHINESE JOURNAL OF CHEMISTRY
卷 35, 期 11, 页码 1673-1677

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201700191

关键词

Beckmann rearrangement; oganocatalyst; ketoximes; amides

资金

  1. Shaanxi Provincial Key Laboratory Project [15JS004]
  2. Baoji University of Arts and Sciences [ZK15046]

向作者/读者索取更多资源

An efficient Beckmann rearrangement of ketoximes was developed using carbon tetrabromide/ triphenylphosphine as an organocatalyst without addition of any acids or metals. The reaction showed good functional group tolerance and gave various amides in moderate to good yields.

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