期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 24, 页码 4278-4283出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201701044
关键词
Amines; C-N bond formation; Cobalt; homogeneous catalysis; Alkylation
资金
- National Natural Science Foundation of China [21673256, 21402208, 21403252]
The methylation of amines using methanol is a promising route to synthesize N-methylamines, and the development of cheap and efficient catalytic system for this reaction is of great significance. Herein, we reported a cobalt (Co)-based catalytic system, which was insitu formed from commercially available Co precursor and a tetradentate phosphine ligand P(CH2CH2PPh2)(3) combined with K3PO4. This catalystic system was very effective for the selective production of dimethylated products from aliphatic amines and monomethylated ones from aromatic amines. The reaction mechanism was further investigated by control and isotope labelling experiments.
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