期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 21, 页码 3818-3825出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700726
关键词
Rhodium; Annulation; Phenols; Alkynes; Naphthols
资金
- NSF of China [21602064, 21572072]
- NSF of Fujian Province [2015 J01056, JA15032]
- Xiamen Southern Oceanographic Center [15PYY052SF01]
- Huaqiao University [ZQN-PY317, 16BS106]
Arene homologation employing internal alkynes as coupling partners and 2-pyridyloxyl as directing group through dual C-H bond functionalization was accomplished using (pentamethylcyclopentadienyl)- rhodium(III) chloride dimer as a precatalyst. This protocol proved tolerant of synthetically valuable functional groups, and provided an expeditious access to highly congested naphthalene derivatives in moderate to good yields. Furthermore, the pyridyl moiety could be removed to furnish the versatile (OH)-free naphthols.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据