期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 359, 期 21, 页码 3729-3734出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201700917
关键词
desymmetrization; organocatalysis; pyrazoles; cross-dehydrogenative coupling; quaternary stereocenter
An enantioselective synthesis of cyclopentenediones bearing a pyrazole unit has been achieved through an organocatalytic Michael addition/oxidation process. This desymmetrization reaction led to the desired pyrazole-cyclopentenediones with high yield and good enantioselectivities. The postulated cross-dehydrogenative coupling-mechanism has been investigated via preliminary control experiments.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据