期刊
ELECTROCHIMICA ACTA
卷 258, 期 -, 页码 208-219出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2017.10.087
关键词
rotating disk electrode catalyst; catalyst coated membrane; proton exchange membrane fuel cell and; polymer electrolyte membrane water; electrolyzer
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
A novel rotating disk electrode (RDE) tip capable of characterizing catalyst coated substrates and compatible with commercial RDE systems is presented. The RDE tip, which uses a top-oriented Ti-based current collector, is demonstrated with Pt foil and commercial catalyst coated membranes (CCM). The specific activity of the platinum foil for oxygen reduction reaction is about 1.55 mA(kinetic) cm(Pt)(-2) in 0.1 M HClO4 at room temperature (20 degrees C), which is in agreement with the measurements reported for poly-crystalline Pt. The Ti-based current collector leads to a very small (approximate to 5.6%) loss in the electrochemical surface area (ECSA). Hydrodynamic calculations and oxygen reduction measurements confirm that even at the fastest rotation speeds used in this type of measurement (i.e., 1600 rpm), the laminar flow regime (Re approximate to 56) is maintained, allowing one to apply classical RDE analysis. Repeatable and high quality cyclic voltammograms (CVs), oxygen reduction curves, and mass and specific activities for commercial CCMs were obtained in 0.1 M HClO4 at room temperature (20 degrees C). The activities determined from these experiments are in agreement with those of the H-2/O-2 fuel cell measurements under equivalent operating conditions. Degradation of the CCM's catalyst during a 30,000 potential cycling accelerated degradation test (ADT) is performed using a 0.4 mg(Pt) cm(-2) commercial CCM and shows an ECSA loss of z 0.0010 m(2) g(Pt)(-1) cycle(-1) and a mass activity loss of approximate to 1.8 x 10(-6) A mg(Pt)(-1) cycle(-1). Details of the design, implementation, and results of this economical and novel approach for characterization of CCMs are presented and discussed. (c) 2017 Elsevier Ltd. All rights reserved.
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