期刊
CHEMICAL SOCIETY REVIEWS
卷 46, 期 24, 页码 7650-7667出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7cs00684e
关键词
-
资金
- National Science Foundation [CHE-0552221]
- Department of Energy [DE-FG03-98ER14879, DE-SC0015997]
- Air Force Office of Scientific Research [FA9550-15-0305]
The dynamics of chemical reactions are often governed by transient species, including the transition state for activated bimolecular reactions. Such transient species are difficult to study experimentally, but it has proven valuable to prepare and probe transition-state dynamics by the photodetachment of anions with an equilibrium geometry similar to the neutral transition state. In this review, recent experimental advances in photoelectron and photoelectron-photofragment coincidence spectroscopy are discussed, as well as the latest progress in the calculation of multidimensional potential energy surfaces and quantum dynamics calculations that have enabled an extension of studies of transition-state dynamics to increasingly multidimensional polyatomic systems. Examples of important dynamical effects such as mode specificity, tunneling, resonance and product energy disposal in reaction dynamics are discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据